Saturday, October 12, 2019

Short Wedding Toasts to the Bride and Groom :: Wedding Toasts Roasts Speeches

Short Wedding Toasts to the Bride and Groom Nature of Love All beings by nature are lovers, as ice by nature is water. The love shared by one couple is powerful enough to unite heaven and earth. May God grant you two many years to live, for earth has few angels. Peace and Plenty May peace and plenty be the first To lift the latch to your door, May happiness be guided to your home. Walk in Love Walk in love, sit in love, live in love. To be in love is to truly live. Your Eye The eye with which you see your wife is the same eye with which your wife sees You. Love Each Fragment If you seek love in each separate fragment of your relationship, you will be overwhelmed by the totality. Who Are You ? Find out who you are as a couple. Then all else will be known. The Desire of God In the desire of God to know his own beauty, you exist. Worldly Power Worldly possessions and power means little. The unsayable, jeweled private life you develop as a couple, means much. Perfect Love When a relationship is perfectly balanced, perfect love can be realized. Psalm 1 (8th century BC) Blessed are they who delight in the way things are, and keep their hearts open day and night. Love Gives Life Love gives life to all the world. Love gives strength and wisdom. May you two walk in beauty, and may your eyes behold many a red and purple sunset. May your ears hear the true voice of your partner. My you be wise so that you may understand what is truly important in life. My you remain calm and strong in the face of all that comes towards you. My you learn the lessons hidden in every leaf and rock. My you seek pure thoughts and act with the intention of helping others. My you find compassion without allowing empathy to overwhelm you. My you seek strength, not to be greater than others, but to fight for the week. My you two always greet each other with clean hands and straight eyes. So when life fades, as the fading sunset, your spirits may continue without shame. May You Be Poor! May you be poor in misfortune, Rich in blessings, Slow to make enemies, And quick to make friends. But rich or poor, quick or slow, May you two know nothing but happiness From this day forward. Let’s all toast this beautiful couple! A Long Life Together A toast to your coffin. May it be made of 100 year old oak.

Friday, October 11, 2019

Multistep Synthesis of Benzilic Acid

Multi-Step Synthesis of Benzilic Acid from Benzoin Abstract: The main purpose of this experiment was to convert a secondary alcohol to a ketone, utilizing a mild and selective oxidizing agent. In addition, this converted alpha diketone was then subjected to rearrangement to a carboxylate salt, then acidification, to produce an alpha-hydroxyacid. In this experiment, benzoin was used and converted into benzil, which was then used to synthesize benzillic acid. The yields were not ideal: . 081g of benzil- a 27. 5% yield; . 038g of benzilic acid- a 34. 7% yield. The matching melting points and IR readings, however, confirmed a high degree of purity for each compound: 95. 6 °C for benzil, and 104. 5 °C for benzilic acid, meager . 632% and . 333% discrepancy from literature values, respectively. Finally, the IR absorption frequencies on the attached graphs illustrate the successful removal of the alcohol in the oxidation step and successive return of the alcohol/creation of carboxylic acid, following rearrangement. Multistep syntheses are essential to producing complex molecules.This experiment illustrated the importance of verifying intermediary products are pure, by utilizing different techniques such as IR and melting point. Below is a diagram of the overall reaction. First Reaction: Second Reaction: Introduction: The multistep reaction from Benzoin to Benzillic acid involves multiple organic chemistry concepts, such as oxidation and re arrangement. The first part of the experiment involves the oxidation of benzoin to benzil, utilizing a mild oxidating agent. The process of oxidation is used in all organic chemistry labs and is essential to a wide variety of synthesis reactions.In addition, oxidation reactions are essential in the the biochemistry of most living organisms. This experiment also breaks down oxidizing agents into selective and non-selective agents. For this experiment’s purposes, nitric acid was used, as it is selective towards secondary alcohols, oxidizing them to ketones. The second part of this experiment involves the rearrangement of benzil to benzillic acid or, more generally, the reaction of an alpha-diketone to an alpha-hydroxyacid. This reaction was first conducted by Justus von Liebig in 1838 (1).The basics of this reaction involve the formation of a carboxylate salt from an alpha-diketone; acid is then added to produce an aromatic alpha-hydroxyacid. The reaction conducted in this expe riment is an essential base step in the synthesis of pharmaceuticals and certain hallucinogenic drugs. The synthesis of Benzil from Benzoin is shown below: The above reaction shows the condensed oxidation of benzoin to benzil. The following diagram shows the condensed reaction of benzil to benzillic acid. Rearrangement occurs to form a salt, then the salt is acidified to form benzillic acid.Once the products of each step were obtained- benzil and benzillic acid- their melting points and IR readings were obtained. These two measurements were used to prove that the correct product was formed without any impurities. One of the major risks in this experiment is loss of product through multiple filtrations. To minimize this problem, the filtration steps should be carefully and slowly executed. This ensures that the least amount of reactants are lost. In addition, recrystallization can occur too quickly if a hot solution is directly placed in an ice bath, allowing impurities to be trapped within the precipitate’s crystal lattice.To avoid this, the solutions should be given ample time to cool to room temperature before adding the solutions to an ice bath. These precautions were taken to try to reach our goal of a high percent yield of product with little to no impurities. There were no new techniques used in this experiment, however there were old techniques used to provide information/obtain a product. The first technique was crystallization which was useful to obtain a solid product that can then be purified. Another old technique utilized was filtration, via hirsch funnel and vacuum. This technique was used to obtain a purified product, removing impurities.Once the final solid product was obtained in both reactions the melting point procedure was used to determine the level of remaining impurity of the final product, comparing the experimental and expected values found in literature. In conjunction with the melting point procedure, infrared spectroscopy was used to reveal the different functional groups of the products. In other words, the IR machine indicates whether our final product matches up with the desired one, matching carbonyl and alcohol absorption peaks (or the lack thereof) to their theoretical presence (either benzil or benzillic acid).Procedure: 1. 5ml of nitric acid was added to . 30g of benzoin in a conical vial with a stir vane. The mixture was then heated in a 70 degree Celsius water bath, while stirred, for one hour. The mixture in the conical vial was then cooled to room temperature and, using a pipette, the solution was transferred to a beaker containing 4ml of ice water. The mixture slowly crystallized in the beaker and the crystallized product was filtered on a hirsch funnel with vacuum. 5 ml of cold water was used to wash the product and then the product was allowed to dry.The solid product was then collected from the funnel and added to a hot 95% ethanol solution in an Erlenmeyer flask and completely dissolved . Once the solid was dissolved completely, the solution was allowed to cool to room temperature. Once yellow crystals formed, the solution was placed into an ice bath. The product was then collected and filtered again on a hirsch funnel with vacuum. The product was then washed with ice cold 95% ethanol. Once completely dried, the crystals were weighed and the final mass, percent yield, melting point, and IR reading of the crystallized product measured/calculated. 100g of benzil and . 30ml of ethanol were mixed in a conical vial.The solution in the conical vial was then heated to about 100 degrees celsius until the benzil dissolved. Then . 25ml of potassium hydroxide was added dropwise to the vial. The mixture was then heated to 110 degrees for 15 minutes, then allowed to slowly cool to room temperature. The product was transferred with a pipette to a 10ml beaker and cooled in an ice bath for 15 minutes. 1ml portions of ethanol were added once crystallized and filtered. The product w as then transferred to a 10ml beaker with 70 °C water, allowing the product to dissolve. 0. ml of HCL acid was added dropwise and the mixture was allowed to cool and then transferred to an ice bath. The crystals were collected on a hirsch funnel and washed with 4ml of cold ice water.The crystals were dried and collected for final mass, percent yield, melting point, and IR reading. Results and Discussion: Table 1: Mass and Molar Quantity of Starting and Synthesized Materials; Percentage Yield and Both Experimental and Theoretical Melting Points of Products and Percent Discrepancy| Compound| Mass (g)| Quantity (mol x10-4)| % Yield| M. P. EXP ( °C)| M. P. THEO ( °C)| % D| Benzoin| 0. 298| 14| -| -| -| -| Benzil Yield| 0. 081| 3. 5| 27. 50%| 95. 6| 95. 0| 0. 632%| Benzil Start| 0. 1001| 4. 76| -| -| -|   | Benzilic Acid Yield| 0. 038| 1. 67| 34. 97%| 149. 5| 150| 0. 333%| The initial mass of benzoin and its yield of benzil in the first part of the experiment, as well as the star ting mass of benzil and its yield of benzilic acid in the second part.Note that the yield from part 1 was not the same amount used at the start of part 2. Also shown: the converted molar quantity of each mass and corresponding percent yield for the two synthesized compound, as well as their experimental and theoretical melting points and percent discrepancy between these values. As noted, the â€Å"Start† weight of Benzil- in row 3 of Table 1- differs from the â€Å"Yield† weight- in row 2. The yield, itself, was not used in the second part of this experiment: the synthesis of benzilic acid from benzil. Furthermore, an error occurred in the second portion of the experiment and very little acid product was salvaged; thus, the yield shown for benzilic acid is data that has been shared from another synthesis (this product yield was from _____ and his lab partner). Additionally, this alternative product was the one used in determining a melting point. Graph 1 illustrates t he successful oxidation of benzil, as the alcohol has been eliminated. As expected, it also retains a strong peak at ~1657cm-1, indicating the carbonyl groups present in the diketone, although this is a slightly lower absorption than expected. Graph 2 also presents a successful synthesis, as a relatively strong and somewhat broad peak appears around 3390cm-1, suggesting the reemergence of an alcohol and potential presence of the carboxylic acid; that the peak at 1715cm-1 remains strong, confirms his.SAMPLE CALCULATIONSCalculation of Benzil Percent Yield: Moles BenzilMoles Benzoin=. 081g? 210. 23g/mol. 298g? 212. 24g/mol=3. 85? 10-4mol14. 0? 10-4mol=0. 275? 100%=27. 5% Calculation of Benzilic Acid Percent Yield: Moles Benzilic AcidMoles Benzil=. 0380? 228. 25g/mol. 1001? 210. 23g/mol=1. 67? 10-4mol4. 76? 10-4mol=0. 3497? 100%=34. 97% Calculation of Percent Discrepancy in Benzil Melting Point: %D=xTHEO-xEXPxTHEO? 100%= 95. 0? -95. 6? 95. 0? =. 00632Ãâ€"100%=0. 32% Calculation of Perc ent Discrepancy in Benzilic Acid Melting Point: %D=xTHEO-xEXPxTHEO? 100%= 150. 0? -149. 5? 150. 0? =. 0033Ãâ€"100%=0. 33% Both steps of this experiment’s synthesis are considered successful. Though not in the desired quantities, a product of benzil was obtained from benzoin and that of benzoic acid from benzil. The initial step, synthesis of benzil, resulted in a yield of 27. 5%, despite an encouragingly smooth synthesis. The synthesis may have called for a second, more thorough recrystallization to appeal this yield.The recrystallization was performed correctly; however, the mixture was likely not allowed to cool at an ideally slow rate. It was removed from the hot plate and, shortly thereafter, transferred to the ice bath- likely, before it had calmed to room temperature. This could have interrupted the ability for the product to crystallize without impurities being trapped within its lattice. During the second portion of this experiment, a known, pure quantity of benzil w as used to synthesize a 34. 97% yield of benzilic acid. This small yield is likely also due to factors similar to the aforementioned.Additionally, the recorded yield was shared from another synthesis; the original synthesis performed yielded too small and impure an amount of product to effectively determine a melting point and I. R. spectra. This failure may certainly be attributed to an error during the recrystallization, prior to the initial filtration. Proper care was taken to allow the solution to cool very slowly during this second recrystallization. Unfortunately, once the solution was transferred to the ice bath, a large chunk of ice crystals somehow fell over the lip of the flask and into the mixture. Being that the intermediate was relatively water

Thursday, October 10, 2019

How Archduke Franz Ferdinand was Assasinated

Franz Ferdinand, the heir to the Austria-Hungarian throne, has been assassinated along with his wife, at the age of 65, while he was invited to travel to Bosnia in order to observe military manoeuvres and open the state museum in Sarajevo. Although he was aware of the many dangers of such an act, the Bosnians desperate fervour for independence and the many terrorist organizations intent upon destroying our government; his love of the low-class wife blinded him. He was permitted to be seen in public with his beloved wife only while acting as â€Å"Military inspector† which was what brought him to set out on these types of trips. The Serbian Military Intelligence was most intent upon this assassination, due to their highly arrogant and crafty ambitions: to take over Bosnia which we have rightfully acquired. It was, therefore, not a surprise when we received first-hand reports proving it was the Serbian Intelligence who were directly responsible for backing the particular group of terrorists who committed these acts. However this did not detract from Franz Ferdinand's foolish actions, which as you will see were in sharp contrast to our honourable and wise King's decisions, when he visited Bosnia: First of all King Franz Joseph had policemen around the streets to protect him, whereas Franz Ferdinand had less than 120 policemen to protect him. King Joseph kept his itinerary top secret, far from the view of suspicious organizations, whereas Franz Ferdinand had his whole itinerary published in the media. On top of that he chose to ride in the â€Å"Grif & Stift† roofless, with his feathery hat sticking out of the vehicle. After brief inspections of the military barracks, the archduke's first stop was the Town Hall via Sarajevo's main road, the Appel Quay. Unknown to the distracted police forces, six young men were lined up across the Appel Quay with Weapons supplied to them from the Serbian Intelligence. Although 5 out of 6 of the assassins did not respond when the procession passed them, Nedeljko Cabrinovic did. He hurled a hand grenade at the archduke†¦ ut he had hit it faster than was required. Moreover it bounced off the back of the vehicle the Archduke was riding in and it blew up on the car behind the archduke's. After realising the situation, the driver accelerated, thus causing Princip to miss his first chance of assassination, and the procession reached the town hall. Here the Archduke cancelled the remainder of his program and advised his officials to utilise a different route to the one already advertised. Unfortunately he forgot to inform the chauffeurs, which would cost him his life. Gavrillo Princip, already dying from Tuberculosis and determined to die as a martyr, was thrown into deep confusion after his group had failed their assassination. He was on his way home when he spotted the vehicle†¦ He stepped forwards, fired two shots at the Archduke and waited. The first shot struck the archduke in his neck, cutting off his jugular vein, rendering his bullet proof covering useless while the second shot hit the duchess in her abdomen. The archduke's last words were, â€Å"Sophie dear! Sophie dear! Don't die! Stay alive for our children! â€Å". It was thus that his love for his low-class wife bought his death†¦

Fables and Short Stories. the Fox and the Grape vs. a Pair of Tickets

Reading Fables and Short Stories Fables, parables and short stories all tell a story and all try to relay a meaningful message or moral. Fables tend to be shorter, use animals and clearly state the moral the author is trying to portray. Parables also tell a story and portray a message, but it basically illustrates a moral or religious lesson. Therefore, I guess it is safe to say that all parables can be fables but not all fables can be a parable. Short stories however tend to be a lot longer than a fable or parable and also use a lot of literary elements.These elements are plot, settings, point of view, characters, dialogue and others. In this essay, I will be talking about Aesop’s fable, â€Å"The Fox and the Grapes† and Amy Tan’s short story, â€Å"A Pair of Tickets. † I will try to explain the morals for each story and how the author portrays these morals. Aesop’s fable, â€Å"The Fox and the Grapes,† is a very short fable with a really bi g moral. It is simply a story about a famished fox trying to find food. He finally stumbles upon ripe grapes. However, instead of complaining that they are out of his reach, he concludes that they were inadequate and not good for eating.The reason this fable catches my attention is because I am amazed on how Aesop can put such an important moral in the fable by using a fox and grapes. Also, the fable is so short but also has such a big meaning. I believe there are many morals in the stories, such as, you can’t always get what you want. However, the main moral of this story, which is very clearly stated, is, â€Å"it is easy to despise what you can’t get† (Aesop 7). Since this fable is so short and has such a powerful moral, it is very easy to remember, making it very easy to retell. This fable also has such a hysterical plot twist and this is what makes it a great fable.The fox is supposedly so hungry but when he can’t reach the grapes, he all of a sudden is not hungry anymore and does not find the grapes appealing. This is why I think ‘plot twist’ is the most important part of a fable because it is when the moral is given to us. The short story, â€Å"A Pair of Tickets† by Amy Tan is about an American woman of Chinese descent who is struggling to accept her Chinese heritage. Jing-mei is the protagonist in this story and she is traveling to China with her father to meet her family and to understand her Chinese culture. The element that is most intriguing to me in this story is symbolism.I realize this when Jing-mei is on a train in China to go visit her family and it is so hot that the makeup on her face begins to literally melt off her face. â€Å"But I had not expected the heat in October. And now my hair hangs limp with humidity. I wear no makeup; in Hong Kong my mascara had melted into dark circles and everything else had felt like layers of grease. So today my face is plain, unadorned except for a thin mist of shiny sweat on my forehead and nose† (Tan 148). I believe the melting of the makeup symbolizes her acceptance of her Chinese heritage and is becoming a whole new person.It also symbolizes that she is growing up and finally realizing how important your heritage is to you and how it shapes the person you are. While Jing-mei is on this trip, I think she begins to realize that her family is more like her than she thought. When she meets her father’s family, her cousin Lili, she says, â€Å"I hold up the Polaroid camera, beckoning Lili with my finger. She immediately jumps forward, places one hand on her hip in the manner of a fashion model†¦ † (Tan 150). I think this is when she first realizes that maybe she isn’t that much different than her family in China.She probably thinks back at when she was younger and remembers that she had pose in the same manner her cousin Lili did. The other realization Jing-mei has that her family and China isn’t t hat much different than her and America is when she enters the hotel. â€Å"The hotel is magnificent. A bellboy complete with uniform and sharp-creased cap jumps forward begins to carry our bags into the lobby† (Tan 151). The hotels are as nice as she has most likely seen in America. She was most likely expecting a small hotel with nothing but a bed in the room. The hotel is also like a shopping mall with a bunch of shops in it.I believe all these things make Jing-mei realize she isn’t that different then the family she never knew and how important family is. In conclusion, Aesop’s fable, â€Å"The Fox and the Grapes, as well as Amy Tans short story, â€Å"A Pair of Tickets,† have a moral. Obviously, it is easier to find the moral in the fable, which is, it is easy to criticize something you can’t have. Howev11er, I believe the moral in â€Å"A Pair of Tickets,† is never lose sight of where you came from, always remember that family comes f irst and that you’re background and where you come from helps build your character.I don’t think it is wrong to reduce a short story to a simple ‘moral’ as one usually does in a fable or parable. I believe every writer writes his or her story to make a point or to teach a lesson. I think the writer is happy when the reader learns a lesson from his or hers stories. When writers use plot, setting, characters, or other literary elements, I believe they do this to paint a clearer picture for the reader so the reader can really understand the moral the author is trying to relay through the story.

Wednesday, October 9, 2019

Sysco Case Assignment Example | Topics and Well Written Essays - 1750 words

Sysco Case - Assignment Example se of business information systems is to predict certain patterns or trends that might otherwise escape the attention of management because of the difficulty of assessing such a big amount of raw data. This is where business information systems can provide their utility. The new term to designate this specific type of computer software is business analytics that is taking the world of business by storm. This new very potent tool has been called as the science of winning (Davenport & Harris, 3). Analytics has been used for a variety of ways to enhance a distinctive capability usually overlooked before due to the sheer mass of data and the difficulty of making sense out of it without the help of sophisticated quantitative analysis. In general, analytics (the newer term) goes a step further than old business information systems (BI) by producing quality data-driven insights that can be used by astute management in producing impressive performance not otherwise attainable before. The amazing power of analytics can be leveraged in a number of ways limited only by the imagination of the owner. Among these possibilities are identifying the most profitable customer segments and how to serve them best, introduce new products, improve the service or offer a better price. SYSCO was founded in Houston, Texas back in 1969 and today is the largest US food distributor. Its main customers are institutional clients such as hotels, restaurant chains, health care-related institutions, educational facilities and lodging establishments. As a measure of its size, company has 420,000 customers, 8,000 marketing associates and some 9,000 delivery associates. Overall, SYSCO has 45,000 employees as of December 2002. In a way, SYSCO is just sort of like any distributor that needs to manage its supplier relationships in a meaningful and tight way that ensures prompt deliveries at less cost. Due to its expertise and efficiency, it can unload a billion cases of product per year without major

Tuesday, October 8, 2019

Burger King's Position on Ethics Term Paper Example | Topics and Well Written Essays - 1500 words

Burger King's Position on Ethics - Term Paper Example Guiding Documents First, Burger King has ethics policy documents guiding aspects of the firm’s operations. One of the four documents is the Code of Business Ethics and Conduct which guides the overall firm operations. Through this policy, Burger King commits to â€Å"†¦taking no ethical shortcuts of any kind. Integrity and honesty are simply not optional† (Burger King Corporation, 2009). The other one is the Code of Business Ethics and Conduct for Vendors that guides vendors on internal and customer relations to ensure ethical practices. The Code of Conduct for Directors is Burger Kings third ethical policy document. This document details the ethical execution of the directors’ roles in the firm. The last document the Code of Ethics for Executive Officers (Appendix 1) also explains how the senior management at Burger King ought to execute their functions in an ethical manner. The document acknowledge the special challenges posed by occupying leadership posit ions and the ethical dilemmas faced, and then details the steps that ensure ethical carriage of duties. Together, these four policy documents exhaustively establish Burger King’s position on ethics in all the firm’s operations (Investor Relations, 2009). ... Burger King’s budget on Lobbying is considerably high- $135,289 in 2010- from which we can discern maintenance of a public position on ethics through the connection of the Vice President heading ethics and being a lobbyist. However, Burger King concentrates on internal mechanisms to ensure ethical operations and does little on a public ethics position. This is a major fail on the part of the firm as issues on ethics are largely swayed by the public’s perception. Internal Guidelines The internal guidelines on ethics revolve around guiding matters of inclusion and diversity, conflicting interests, data privacy, financial reporting, food and drink safety and quality, hiring practices, communicating with the outside world and protecting the environment among other important aspects. The internal guidelines aim at ensuring ethics forms an important part of Burger King’s company culture and hence are exhaustive, covering all possible aspects at which ethical considerat ions and dilemmas may arise. These Codes of Ethics policy documents for the different levels of workforce- employees, vendors, directors and executive officers- effectively cover aspects of employee-employee and employee-public interactions. Defined Process The Burger King Corporation (2009) details the internal process to follow in case of a breach of ethics; first, each employee has to understand the firm’s ethical policies. In cases where an employee discerns a breach of the firm’s ethical policy, he/she should report to the chief of ethics, compliance officer, human resource representative or attorney from the law department. Such information will only be disclosed to the relevant parties, with the reports taken seriously and promptly investigated. However,

Monday, October 7, 2019

The Chinese and American Educational Systems Essay

The Chinese and American Educational Systems - Essay Example In the meanwhile, they lose a lot of fun, and that’s also a big part of school life, in my point of view. In China, only professional athletic students are on the sports team. In the U.S., almost everybody plays at least one sport. American schools offer sports that almost every student can play for competition and fun. At my U.S. high school, when it was my turn to join a sports team, I found out I couldn’t even try a lot of sports on the list. It was almost impossible to pass the try-outs, but I was still encouraged to join a sport. From birth, Asian children are told to be perfect, no matter how they feel about tasks, how much it costs, how long it takes. If you surveyed Chinese and American students, I bet most Chinese kids couldn’t name five things they like. They’re always resting in their spare time to relax from the overwhelming stress. American students work hard too, but seek fun instead of â€Å"perfecting† themselves. Extracurricular activities like drama, debate, and sports keep American students busy and teach us about more than just academics. My schedule is full of AP classes, but compared with 13 hours of classroom work a day in a Chinese high school, I don’t feel much pressure. After growing up in my academic-oriented culture, I find it’s pretty easy for me to get on the honor roll or scholar’s list in my American high school. There are diligent American kids who get a higher GPA than I do, of course. And worldwide, high school students who win creativity contests are always Americans. So I deem the U.S. educational system is as effective as the Asian system, just in a different way. Cultural values in the United States encourage equality in the educational system, as a general rule. In the U.S., people hold different political ideologies: liberal or conservative.Â